Prediction of transboundary pollution of air and soil in Odesa region by fly ash from Moldavian SDPP

Authors

DOI:

https://doi.org/10.15276/opu.1.71.2025.14

Keywords:

fly ash, transboundary pollution, soil pollution, fractional composition

Abstract

Since at present, due to the lack of gas, a large energy enterprise Moldavian SDPP has returned to the use of solid fuel (coal), the problem of fly ash pollution of the territory of Odesa region has become relevant again. The article proposes a method for calculating the dispersion of solid particles with a shape close to spherical on the soil surface on the example of transboundary pollution of Odesa region by fly ash from power boilers of the Moldavian SDPP. In contrast to the current UND-86 standard, the method uses the general laws of aerodynamics and is based on determining the settling velocity of solid particles. It has been shown that, although fly ash from pulverised coal boilers consists of a large number of different substances, the bulk of it is silica, aluminium, iron and calcium oxides. They differ in fractional composition and material density. The proposed method takes this difference into account and allows predicting the coordinates of fly ash particles of a particular material and a certain size falling on the soil. The calculations showed that the chemical composition of soil pollution varies along the smoke plume line, with iron oxides predominating in the northern part of Odesa district and silicon dioxide in the immediate vicinity and in Odesa city. Due to the lack of reliable data on the fractional composition of fly ash from Moldavian SDPP, only an approximate estimate of dispersion was possible. However, even such estimates allowed us to conclude that ash particles spread much deeper into the territory of Odesa Oblast than according to the results of the UND-86. This is the basis for revising this methodology in terms of calculating the dispersion of fly ash from thermal power plants.

Downloads

Download data is not yet available.

References

Kang, S. H., Heo, J., Oh, I. Y., Kim, J., Lim, W. H., Cho, Y., & Oh, S. (2016). Ambient air pollution and out-of-hospital cardiac arrest. International journal of cardiology, 203, 1086–1092. DOI: 10.1016/j.ijcard.2015.11.100. (date of access: 10.02.2025).

Zhao, B., Johnston, F. H., Salimi, F., Kurabayashi, M., & Negishi, K. (2020). Short-term exposure to ambient fine particulate matter and out-of-hospital cardiac arrest: a nationwide case-crossover study in Japan. The Lancet Planetary Health, 4(1), e15-e23. Retrieved from https://www.thelancet.com/action/showPdf?pii=S2542-5196%2819%2930262-1. (date of access: 10.02.2025).

Brauer, M., Brook, J. R., Christidis, T., Chu, Y., Crouse, D. L., Erickson, A., & Burnett, R. T. (2019). Mortality-air pollution associations in low-exposure environments (MAPLE): Phase 1. Health Effects Institute. Retrieved from https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7334864/. (date of access: 11.02.2025).

Brauer, M., Brook, J. R., Christidis, T., Chu, Y., Crouse, D. L., Erickson, A., & Burnett, R. T. (2022). Mortality-air pollution associations in low exposure environments (MAPLE): Phase 2. Health Effects Institute. Retrieved from https://pubmed.ncbi.nlm.nih.gov/36224709/. (date of access: 10.02.2025).

Hassan, M. A., Mehmood, T., Lodhi, E., Bilal, M., Dar, A. A., & Liu, J. (2022). Lockdown amid COVID-19 ascendancy over ambient particulate matter pollution anomaly. International Journal of Environmental Research and Public Health, 19(20), 13540. Retrieved from https://www.mdpi.com/1660-4601/19/20/13540. (date of access: 12.02.2025).

Li, H., Zhao, Z., Luo, X. S., Fang, G., Zhang, D., Pang, Y., & Tang, M. (2022). Insight into urban PM2.5 chemical composition and environmentally persistent free radicals attributed human lung epithelial cytotoxicity. Ecotoxicology and Environmental Safety, 234, 113356. DOI: https://doi.org/10.1016/j.ecoenv.2022.113356.(date of access: February 13, 2025).

Singh, P. K., Shikha, D., & Saw, S. (2023). Evaluation of potential toxic heavy metal contamination in soil, fly ash, vegetables and grain crops along with associated ecological and health risk assessment of nearby inhabitants of a thermal power plant in Jharkhand (India). Environmental Science and Pollution Research, 30(3), 7752–7769. DOI: https://doi.org/10.1007/s11356-022-22638-0. (date of access: 11.02.2025).

Ge, J. C., Yoon, S. K., & Choi, N. J. (2018). Application of fly ash as an adsorbent for removal of air and water pollutants. Applied Sciences, 8(7), 1116.

Fidanchevski, E., Angjusheva, B., Jovanov, V., Murtanovski, P., Vladiceska, L., Aluloska, N. S., & Dolenec, S. (2021). Technical and radiological characterization of fly ash and bottom ash from thermal power plant. Journal of Radioanalytical and Nuclear Chemistry, 330, 685–694. Retrieved from https://link.springer.com/article/10.1007/s10967-021-07980-w. (date of access: 10.02.2025).

Komljenović, M., Petrašinović-Stojkanović, L., Baščarević, Z., Jovanović, N., & Rosić, A. (2009). Fly ash as the potential raw mixture component for Portland cement clinker synthesis. Journal of thermal analysis and calorimetry, 96, 363–368. DOI: https://doi.org/10.1007/s10973-008-8951-0. (date of access: 12.02.2025).

Kramar, S., Žibret, L., Fidanchevska, E., Jovanov, V., Angjusheva, B., & Ducman, V. (2019). Use of fly ash and phosphogypsum for the synthesis of belite-sulfoaluminate clinker. Materiales de construcción, 69(333), e176–e176. DOI: 10.3989/mc.2019.11617. (date of access: 1002.2025).

Lingling, X., Wei, G., Tao, W., & Nanru, Y. (2005). Study on fired bricks with replacing clay by fly ash in high volume ratio. Construction and building materials, 19(3), 243–247. DOI: https://doi.org/10.1016/j.conbuildmat.2004.05.017. (date of access: 12.02.2025).

Zeng, L., Sun, H. J., Peng, T. J., & Zheng, W. M. (2019). The sintering kinetics and properties of sintered glass-ceramics from coal fly ash of different particle size. Results in Physics, 15, 102774. DOI: https://doi.org/10.1016/j.rinp.2019.102774. (date of access: 11.02.2025).

Hlushchuk, V., Snihur, O., Ivanenko, O., Kovbasiuk, V., Marchuk, Yu., & Sezonenko, O. (2023). Adsorption and desorption of hydrogen on carbon nanotubes. Bulletin of Kremenchuk Mykhailo Ostrohradskyi National University, 4(141), 48–56. DOI: https://doi.org/10.32782/1995-0519.2023.4.6. (date of access: 28.02.2025).

Gollakota, A. R., Volli, V., & Shu, C. M. (2019). Progressive utilization prospects of coal fly ash: A review. Science of the Total Environment, 672, 951–989. DOI: https://doi.org/10.1016/j.scitotenv.2019.03.337. (date of access: 11.02.2025).

Ullah, A., Kassim, A., Abbil, A., Matusin, S., Rashid, A. S. A., Yunus, N. Z. M., & Abuelgasim, R. (2020). Evaluation of coal bottom ash properties and its applicability as engineering material. IOP Conference Series: Earth and Environmental Science, 498(1), 012044. DOI: 10.1088/1755-1315/498/1/012044. (date of access: 11.02.2025).

Sajwan, K. S., Paramasivam, S., Alva, A. K., Adriano, D. C., & Hooda, P. S. (2003). Assessing the feasibility of land application of fly ash, sewage sludge and their mixtures. Advances in Environmental Research, 8(1), 77–91. DOI: https://doi.org/10.1016/S1093-0191(02)00137-5. (date of access: 13.02.2025).

Kumpiene, J., Lagerkvist, A., & Maurice, C. (2007). Stabilization of Pb- and Cu-contaminated soil using coal fly ash and peat. Environmental Pollution, 145(1), 365–373. DOI: https://doi.org/10.1016/j.envpol.2006.01.037. (date of access: 11.02.2025).

Alterary, S. S., & Marei, N. H. (2021). Fly ash properties, characterization, and applications: A review. Journal of King Saud University-Science, 33(6), 101536. DOI: https://doi.org/10.1016/j.jksus.2021.101536. (date of access: 10.02.2025).

Gopinathan, P., Santosh, M. S., Dileepkumar, V. G., Subramani, T., Reddy, R., Masto, R. E., & Maity, S. (2022). Geochemical, mineralogical and toxicological characteristics of coal fly ash and its environmental impacts. Chemosphere, 307, 135710. DOI: https://doi.org/10.1016/j.chemosphere.2022.135710. (date of access: 11.02.2025).

Fly ash. (2025, February 13). In Wikipedia. Retrieved from. https://uk.wikipedia.org/wiki/%D0%97%D0%BE%D0%BB%D0%B0_%D0%B2%D0%B8%D0%BD%D0%BE%D1%81%D1%83. (date of access: 13.02.2025).

Butenko, O.H. (2016). Technical hydromechanics. Odesa: Nauka i tekhnika.

Meteoblue. (2025, February 28). Rose of the winds. Retrieved from. https://www.meteoblue.com/uk/weather/historyclimate/climatemodelled/odesa_ukraine_698740. (date of access: 13.02.2025).

Downloads

Published

2025-04-18

How to Cite

[1]
Butenko, O., Melnyk, S., Karamushko, A., Vasiutynska, K., Liesnikov, V. and Zherdenko, V. 2025. Prediction of transboundary pollution of air and soil in Odesa region by fly ash from Moldavian SDPP. Proceedings of Odessa Polytechnic University. 1(71) (Apr. 2025), 119–126. DOI:https://doi.org/10.15276/opu.1.71.2025.14.

Most read articles by the same author(s)

1 2 > >>